01 -
In a medium heatproof bowl, add the chocolate, cocoa powder, and espresso powder. Pour hot water over the mixture. Cover and let stand for 5 minutes. Whisk mixture gently until smooth, then set aside to cool.
02 -
Preheat the oven to 350°F (175°C). Butter and flour two 8-inch (20 cm) round cake pans.
03 -
In a small bowl, whisk together the flour, granulated sugar, brown sugar, salt, and baking soda.
04 -
Whisk sour cream, vegetable oil, eggs, egg yolk, vinegar, and vanilla extract into the cooled chocolate mixture until smooth.
05 -
Stir the dry ingredients into the wet ingredients until smooth, being careful not to overmix. The batter will be thin.
06 -
Pour the batter into the prepared pans and bake for 35 to 40 minutes, or until a cake tester or toothpick comes out clean. Cool in the pans for 30 minutes, then carefully turn them out onto a cooling rack to cool completely.
07 -
Combine the sugar, egg whites, and salt in the bowl of a stand mixer. Set the bowl over a saucepan filled with 1 inch (2.5 cm) of gently simmering water. Whisking gently and constantly, heat the mixture until the sugar is dissolved and the mixture is slightly thickened and foamy, about 3 minutes, or until it registers 150°F (65°C) on a thermometer.
08 -
Fit the stand mixer with a whisk attachment. Beat the heated mixture on medium speed until cooled and thickened, about 5 minutes. Add the butter 1 piece at a time until the mixture is smooth and creamy. Add the melted chocolate and vanilla extract, then beat until light and fluffy.
09 -
Place one cake layer on a cake turntable or stand. Spread an even layer of frosting over it, slightly pushing frosting over the edges. Top with the second cake layer, positioning it upside-down for a flat surface. Spread the remaining frosting evenly over the entire cake. Serve or refrigerate for up to 2 days. Allow to come to room temperature before serving.