01 -
Combine the chocolate, cocoa powder, and espresso powder in a medium heatproof bowl. Pour the boiling water over the mixture, cover, and let stand for 5 minutes. Whisk gently until smooth and set aside to cool.
02 -
Preheat oven to 350°F (175°C). Line a standard 12-cup muffin tin with paper liners.
03 -
In a small bowl, whisk together the flour, granulated sugar, brown sugar, fine salt, and baking soda.
04 -
Whisk sour cream, vegetable oil, eggs, egg yolk, vinegar, and vanilla into the cooled chocolate mixture until smooth, scraping the sides and bottom of the bowl.
05 -
Stir the flour mixture into the wet ingredients until smooth, being careful not to overmix.
06 -
Using a spring-loaded scoop, divide the batter evenly among the prepared muffin cups, filling them 3/4 full.
07 -
Bake in the preheated oven for 17 to 18 minutes or until cupcakes are set and firm to the touch.
08 -
Let cupcakes cool in the pan on a wire rack for 10 minutes before transferring to a wire rack to cool completely, about 1 hour.
09 -
In a small saucepan, bring the heavy cream to a simmer. Remove from heat and add the finely chopped semisweet chocolate. Let it stand for a few minutes, then stir until smooth. Cool to approximately 75°F or until thickened but still pourable.
10 -
In a stand mixer using a paddle attachment, combine the butter, powdered sugar, cocoa powder, vanilla, and fine sea salt. Mix on low until blended, increase the speed to medium, and beat for 3 minutes. Scrape down the bowl as needed.
11 -
Reduce the mixer speed to medium-low and add the cooled chocolate cream mixture. Beat until the frosting lightens in color and texture, about 2 minutes, scraping the bowl as needed.
12 -
Frosting can be made 1 day ahead and stored in an airtight container in the refrigerator. Rewarm slightly and stir or rewhip before use.